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Some websites do accept BTC as deposits. I'am not sure about withdrawals though. If you're planning to play online. I'd highly suggest that you play the smallest stakes first and get your feet wet.

have you played at swcpoker.eu ? or sealswithclubs as it was called before... my favorite place to play... only bitcoin there, no normal cash.. needs more players but still good... give it a go if you don't know it...good range of tournaments and ring games.. freerolls to get any noobs started... I only play low stakes but there's often a few high rollers waiting on the more expensive tables looking for a game..