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There is nothing inherently special about the Cayenne pepper for that function. Capsasin may assist in better blood flow.

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4477151/

As such any hot pepper would achieve a similar result.

You will note I specified some of the purported health benefits are wishful thinking. Not all.

Take that witch doctor! Fuck yeah science!

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